Monthly Archives: September 2016

Chemistry, Nature, and Everything Else

My three months of summer were spent living in an AirBnB room in a pretty Swiss house hidden somewhere in the peaceful town of Préverenges, a five-minute walk from the shores of Lac Léman, and working in a small inorganic chemistry lab tucked away in a corner of the CH building in EPFL, where many toxic/radioactive/flammable/pungent, but not in any way less colourful and fascinating, chemical reactions were carried out and studied extensively. It was, perhaps, one of the best summers I could ever remember.

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Préverenges: a pier (I think) on Lac Léman

Inorganic chemistry is a vast field of research, for it covers the syntheses, structures and behaviours of compounds based on virtually any of the elements found in the Periodic Table, except for carbon. Of course, it would be a Herculean task for any one research group to work on all of these elements, so each group tends to choose to focus on a collection of elements that behave similarly to one another, for it is then easier to classify and rationalise any trends and anomalies discovered. For my three months in EPFL, I was attached to the Group of Coordination Chemistry led by Professor Marinella Mazzanti, whose main interest lies in the rich chemistry of lanthanides and uranium. The project to which I was assigned involved an investigation of the structures and reactivity of several lanthanide Schiff-base complexes: the goal was to try to store electrons in these complexes using a strong reducing agent, making them much more nucleophilic, thus enabling them to become very reactive towards the activation of small molecules such as carbon dioxide, carbon monoxide and even molecular nitrogen. This could potentially open up new avenues of research for other fields such as catalysis and synthetic chemistry.

A day-to-day routine in the lab would involve setting up new reactions, analysing on-going reactions using various techniques such as Nuclear Magnetic Resonance (NMR) spectroscopy, Mass Spectrometry, etc. and attempting to isolate pure, crystalline products from completed reactions for further examinations such as single-crystal X-ray diffraction and elemental analysis. Almost everything we do in the lab is air-sensitive, and so special techniques to handle these chemicals under an inert atmosphere must be used to ensure the safety and integrity of our experiments. Of course, the actual picture was somewhat less rosy as very often things never really worked out the way we expected them to, and here came the ever-insightful discussions with more senior members of the group: with their experience, they were able to give very useful advice which helped me get out of the bottleneck and move forward by interpreting the data more precisely and improving on the experiments. I cherished these discussions, for through them I not only gained more understanding of my project in particular, and of f-block chemistry in general, but I also became more bonded to my lab-mates (it is all about forming bonds in chemistry, is it not?).

But my Swiss experience was not just confined within the four walls of the lab. Even though I am not a fantastic fan of travelling, the scenic beauty of Switzerland still managed to compel me to get out of my room every now and then, with some reluctance at first when I had to get up early on a Saturday morning to catch a train, but with full bliss and marvelment by the end of the day after having been immersed in the fresh air and the breath-taking views of nature. That was the time when I walked up the vineyard terraces in Lavaux on a rainy day, hoping to steal a grand look on the many arrays of vines, the wavy surface of the lake and the grey Alps fading into the distance behind the clouds and the rain. It was such serenity to just let myself get lost amongst the cute little houses, hidden staircases and secret streams of water flowing down into the lake. There was no sunlight on that day, but everything still somehow managed to glow up so vividly… Then there was the time I took a vintage train to go up to Rochers de Naye, a mountain of the Swiss Alps with an elevation of around 2000 m above sea level that promises a mesmerising panorama of nearby valleys and of Lac Léman. It was cold and windy up there, so after walking around to absorb as much of the view as possible, it was perfect to just sit down in a local bar and slowly enjoy a cup of hot chocolate.

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Lavaux Vineyard Terraces: a grand view after the rain

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Lavaux Vineyard Terraces: pretty houses

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Rochers de Naye: a panoramic view from the summit

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Rochers de Naye: a botanic garden at ca. 2000 m above sea level

And then there was the time I went to a festival called KleinLaut based in Riniken, which was literally in the middle of nowhere. However, thanks to it being in a small town and hidden among the woods and mountains, it did not get overloaded with people and noises. There were fun activities for everyone — children and adults alike — to engage in, all food was home-cooked, and the bands played handsomely. It was relaxing to just wander around and enjoy the food, the music and the people, in a place far away from crowded and rowdy city centres.

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KleinLaut Festival, Riniken: people having fun

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KleinLaut Festival, Riniken: cute signs making the festival feel a lot homier

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KleinLaut Festival, Riniken: Turbostaat playing — and of course everybody enjoyed the music!

My three months in Switzerland have been a wonderful experience: I have made new friends with my lab-mates and with the other EPFL interns through work as well as through the various picnics and BBQs we organised, learnt a great deal of new chemistry, and been thoroughly amazed by the enthralling beauty of nature. It was hard to say goodbye to my lab-mates, my housemates, and anybody else who has been part of my experience, but I hope that one day I will be able to come back, be it for something long-term, or even just for a short visit, and relive some of the best moments I will always treasure.

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Ouchy, Lausanne: the onset of dusk

Bang Cong Huynh
Peterhouse, University of Cambridge, UK
Group of Coordination Chemistry, EPFL, Switzerland

Switzerland Withdrawals

Sion is a homey town where bus drivers greet pedestrians on the streets, the capital of Canton Valais Wallis, and the site of the EPFL Energypolis campus where I had worked for the past summer. Energypolis consists of seven research laboratories that focus on renewable energy, health and environmental sustainability, lead by professors affiliated with the Institute of Chemical Sciences and Engineering (ISIC) from the main EPFL campus. The various exciting projects include gas separation, hydrogen storage, solar-to-fuel conversion, carbon dioxide capture and storage, and what I worked on: vanadium redox flow batteries (VRBs).

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Dual circuit redox flow battery demonstrator in Martigny

Redox flow batteries is an interesting field of research as it provides a rechargeable electrochemical energy storage system that may be useful in large-scale utility applications, to compensate for the instability of renewable energy sources such as solar and wind. I was very fortunate to be a part of this project in the Laboratory of Physical and Analytical Electrochemistry (LEPA) where I learned a lot about flow batteries in practice: the concept, assembly, and of course the intricacies to improve its efficiency. My task was to test how different membranes and temperatures affected the batteries, but it was much more work than it sounds: setting the correct voltage limits to avoid anodizing the electrode, determining the optimal amount of electrolyte for each set of tests, finding novel ways to keep a constant temperature for the entire apparatus… But these troubleshooting experiences gave me great insights to what a PhD experience would be like. Overall, it was a very fruitful experience!

And of course, traveling! Switzerland is one of the most beautiful countries in the world and it’s also in the center of Europe, which makes traveling very convenient: it takes less than 4 hours to go to Paris and Milan by train, less than 2 hours to fly from Geneva to Barcelona, Munich, Prague, etc., and of course Switzerland itself is simply breathtaking! As many posts have mentioned, Half-fare cards, Track 7, and your fellow wonderful interns will make your trips even more fantastic! Also, many attractions offer significant discounts if you are with a group of 10 or more.

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Jungfrau – “Top of Europe”!

Every weekend was a different adventure. Even though I had to occasionally get up as early as 4 am to catch the train, very frequently run after all forms of transportation, and my leg muscles sure became much stronger after walking an average of 20 miles every weekend, it was worth every moment. Whether it was hiking by the Matterhorn, taking the world’s steepest cogwheel railway up to Mt. Pilatus, or simply strolling by Lake Geneva in Montreux, words cannot express how breathtaking the scenery was:

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hiking by the Matterhorn

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flowers by by Lake Geneva in Montreux

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Mt. Pilatus

After I came back to the U.S., a friend asked which city was my favorite during my three months of interning/traveling in Europe. I could not give a clear answer to this question, but Switzerland was most definitely my favorite country.

Carrol (Qiwen) Xia, University of California, Berkeley.

Laboratory of Physical and Analytical Electrochemistry (LEPA), EPFL

What an amzing country

This summer, I went to EPFL as a Research Intern. And no surprise, it has been one of my best summers ever!

Working at EPFL has been a great experience. I worked at Automatic Control Lab under Mechanical Engineering Department. As a Mechatronics student, it has been a extremely valuable experience to me because the projects here are really innovative and advanced. From bio-robots to UAV, there are robots that you have never imagined. I believe that you will always find a lab that interests you whatever your professional specialization is.

Apart from EPFL, Switzerland is also a beautiful country to visit. Switzerland is not big and transportation is super convenient thanks to SBB ( the Swiss Train company). Its cities are also small enough to just walk around, including the big ones like Zurich and Geneva. And how beautiful is Switzerland? Whenever you pull out your phone/camera, take a picture, and it can me breath-taking.

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(sunset by lake Geneva)

If you are a football fan like me, Zurich is a must on your list. And in Zurich, you have to go to FIFA Museum. Here, the REAL Rimet Trophy is displayed.

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What’s my favorite Swiss city? It has to be Lucerne. Everything is blended well together. The cloud, the river, the bridge, the swans. Perfect.IMG_4223.jpg

There are also great hikes you shouldn’t miss. Pack your toblerones, take a train ride up to Matthorne, eat them before the lake. The experience will make you never forget.IMG_5061.jpg

Also, probably the most legendary hike ever, is the ridge of Interlaken. With the cliffs beside you, every move has to be careful. The view? Astonishing.IMG_5344.jpg

There are just too many things to name,. chocolates, cheese, chess and on and on and on. You have to be there to check it out. If you love to see it by yourself, I would say, EPFL research program is great. And do not miss it. This is life time experience. You will fall in love with this amazing country.

Maxwell

University of British Columbia

Third Year Mechatronics Student